Hydrocyanation, silylation and amination

Intramolecular hydroamination reaction

Intramolecular hydroamination reactions of α, ω-aminoolefins have been studied mechanistically well:

Are lanthanide complexes [LnR (Cp *)2] (Ln = La, Nd, Sm, Y, ...; Cp * = η5-C5Me5; R = H, CH (SiMe3)2, N (SiMe3)2) used as precatalysts, the following reaction sequence has been proven:



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Video: Chemical Synapse Animation (January 2022).